(1s 1 4s 1 ) 3 S He 0
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 3040.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4s- electron | |
| 1 | 1s | .815327 | .22393008 |
| 2 | 2s | 1.020061 | -.30594949 |
| 3 | 3s | .215790 | 2.07559379 |
| 4 | 4s | .250755 | -3.25370467 |
| 5 | 5s | .487951 | .78491560 |
| 6 | 4s | .998172 | -.22386820 |
| 7 | 5s | 6.212327 | -.00119072 |
| 8 | 4s | 10.392285 | -.00040677 |
| 9 | 5s | 31.572772 | -.00003464 |
| 10 | 4s | 58.848591 | -.00000611 |
| ORB.ENERGY,a.u. | -.036544 | ||
| NORM | 1.000020 | < R > | 20.613836 | < R2 > | 478.324751 | < 1/R > | .068846 | < 1/R**2 > | .032145 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 1.945293 | .75732413 |
| 2 | 1s | 2.095832 | .25511853 |
| 3 | 2s | 1.898586 | -.01327115 |
| 4 | 3s | 2.341865 | -.00124202 |
| 5 | 4s | 4.818754 | .00008175 |
| ORB.ENERGY,a.u. | -1.911500 |
| NORM | 1.000000 | < R > | .749920 | < R2 > | .749872 | < 1/R > | 2.000239 | < 1/R**2 > | 8.001760 |
Total Energy= -2.03578083 a.u.
Kinetic Energy= 2.03643664 a.u.
Potential Energy= -4.07221747 a.u.
Virial Ratio = -1.99967796