(1s 2 2s 1 ) 2 S Na 8+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 2020.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 9.537236 | .37269932 |
| 2 | 2s | 4.461729 | -.65999591 |
| 3 | 3s | 5.598203 | -.40677971 |
| 4 | 5s | 10.369035 | -.02557114 |
| 5 | 4s | 21.228904 | .00306505 |
| 6 | 5s | 30.830276 | -.00048395 |
| 7 | 5s | 2.759845 | .00009864 |
| ORB.ENERGY,a.u. | -11.015000 | ||
| NORM | 1.000000 | < R > | .616927 | < R2 > | .443819 | < 1/R > | 2.374542 | < 1/R**2 > | 22.752429 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 10.447711 | .93320997 |
| 2 | 1s | 16.464534 | .05736921 |
| 3 | 2s | 10.856052 | .01575593 |
| 4 | 3s | 6.009960 | .00107541 |
| 5 | 4s | 15.105565 | -.00128612 |
| 6 | 5s | 24.679854 | .00068443 |
| 7 | 3s | 31.365015 | -.00038181 |
| ORB.ENERGY,a.u. | -51.688000 |
| NORM | 1.000000 | < R > | .141414 | < R2 > | .026804 | < 1/R > | 10.676117 | < 1/R**2 > | 229.827094 |
Total Energy= -125.23283865 a.u.
Kinetic Energy= 125.23282918 a.u.
Potential Energy= -250.46566783 a.u.
Virial Ratio = -2.00000008