(1s 2 2s 1 2p 1 ) 1 P Ar 14+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1121.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 7.896780 | .97652165 |
| 2 | 2p | 11.403819 | .03884039 |
| 3 | 2p | 23.875836 | .00382844 |
| 4 | 3p | 6.552312 | .01516177 |
| 5 | 4p | 12.705415 | -.02708982 |
| 6 | 5p | 44.232604 | -.00019772 |
| 7 | 5p | 6.038961 | -.00065435 |
| ORB.ENERGY,a.u. | -29.326000 | ||
| NORM | 1.000000 | < R > | .312979 | < R2 > | .118367 | < 1/R > | 4.028278 | < 1/R**2 > | 21.870560 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 15.130762 | .40849705 |
| 2 | 2s | 7.316848 | -.82503796 |
| 3 | 3s | 9.899964 | -.29354800 |
| 4 | 4s | 28.273471 | .00608512 |
| 5 | 5s | 35.197710 | -.00146392 |
| 6 | 5s | 7.407432 | .00755439 |
| 7 | 3s | 50.927220 | .00009862 |
| 8 | 4s | 4.823385 | -.00050000 |
| ORB.ENERGY,a.u. | -30.577000 | ||
| NORM | 1.000000 | < R > | .367925 | < R2 > | .158225 | < 1/R > | 4.025089 | < 1/R**2 > | 65.853296 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.341834 | .93283837 |
| 2 | 1s | 25.999247 | .05565202 |
| 3 | 2s | 19.432873 | .01532668 |
| 4 | 3s | 8.454391 | .00221830 |
| 5 | 4s | 64.809013 | -.00024548 |
| 6 | 5s | 17.610306 | .00193691 |
| 7 | 3s | 89.451395 | -.00004440 |
| ORB.ENERGY,a.u. | -144.680000 |
| NORM | 1.000000 | < R > | .085547 | < R2 > | .009811 | < 1/R > | 17.631449 | < 1/R**2 > | 625.533606 |
Total Energy= -376.46271810 a.u.
Kinetic Energy= 375.72375798 a.u.
Potential Energy= -752.18647608 a.u.
Virial Ratio = -2.00196676