(1s 2 2s 1 4p 1 ) 1 P Na 7+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1141.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4p- electron | |
| 1 | 2p | 4.381838 | .44274347 |
| 2 | 3p | 2.409059 | -.83519602 |
| 3 | 5p | 2.154573 | 1.49851236 |
| 4 | 4p | 3.153868 | -.45587422 |
| 5 | 5p | 5.118688 | .07907357 |
| 6 | 4p | 10.236078 | -.01752215 |
| 7 | 5p | 23.691164 | -.00244646 |
| 8 | 4p | 39.627321 | -.00074130 |
| 9 | 3p | 1.092419 | .00465576 |
| 10 | 5p | 57.569525 | .00021276 |
| ORB.ENERGY,a.u. | -2.074500 | ||
| NORM | 1.000000 | < R > | 2.770362 | < R2 > | 8.705809 | < 1/R > | .521004 | < 1/R**2 > | .758713 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 9.192689 | .39301777 |
| 2 | 2s | 4.552091 | -.77525506 |
| 3 | 3s | 5.414658 | -.30232816 |
| 4 | 5s | 9.211584 | -.03473851 |
| 5 | 4s | 19.275089 | .00857877 |
| 6 | 5s | 25.571419 | -.00201930 |
| 7 | 5s | 2.443295 | -.00077928 |
| 8 | 3s | 39.931125 | .00008800 |
| ORB.ENERGY,a.u. | -10.530000 | ||
| NORM | 1.000000 | < R > | .618069 | < R2 > | .445508 | < 1/R > | 2.369607 | < 1/R**2 > | 22.664870 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 10.450781 | .94260473 |
| 2 | 1s | 17.105380 | .04939053 |
| 3 | 2s | 12.265567 | .01221447 |
| 4 | 3s | 8.080080 | .00256620 |
| 5 | 4s | 43.424154 | -.00063829 |
| 6 | 5s | 57.722213 | .00023529 |
| 7 | 5s | 5.360587 | .00017621 |
| ORB.ENERGY,a.u. | -49.899000 |
| NORM | 1.000000 | < R > | .141465 | < R2 > | .026827 | < 1/R > | 10.673602 | < 1/R**2 > | 229.742348 |
Total Energy= -127.31732388 a.u.
Kinetic Energy= 127.30639696 a.u.
Potential Energy= -254.62372085 a.u.
Virial Ratio = -2.00008583