(1s 2 2s 1 4p 1 ) 1 P Ar 14+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1141.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4p- electron | |
| 1 | 2p | 7.263691 | .51865445 |
| 2 | 3p | 4.475457 | -1.02244896 |
| 3 | 5p | 3.998796 | 1.53654134 |
| 4 | 4p | 5.876029 | -.38328365 |
| 5 | 5p | 8.912439 | .07451273 |
| 6 | 4p | 18.118530 | -.01106498 |
| 7 | 5p | 42.117883 | -.00144300 |
| 8 | 4p | 70.807631 | -.00040823 |
| 9 | 3p | 2.050762 | .00471578 |
| 10 | 5p | 103.416724 | .00011280 |
| ORB.ENERGY,a.u. | -7.193800 | ||
| NORM | 1.000000 | < R > | 1.500287 | < R2 > | 2.552802 | < 1/R > | .959434 | < 1/R**2 > | 2.516206 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 14.634522 | .43838421 |
| 2 | 2s | 7.897464 | -.81616694 |
| 3 | 3s | 9.517332 | -.30465223 |
| 4 | 5s | 15.850517 | -.02120371 |
| 5 | 4s | 32.347611 | .00430052 |
| 6 | 5s | 43.162456 | -.00089782 |
| 7 | 5s | 4.303448 | -.00046947 |
| 8 | 3s | 67.320740 | .00004166 |
| ORB.ENERGY,a.u. | -32.875000 | ||
| NORM | 1.000000 | < R > | .358795 | < R2 > | .150140 | < 1/R > | 4.123001 | < 1/R**2 > | 68.447275 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.358322 | .93847535 |
| 2 | 1s | 27.371520 | .04903676 |
| 3 | 2s | 21.938236 | .01687145 |
| 4 | 3s | 9.259896 | .00046841 |
| 5 | 4s | 70.053947 | -.00042814 |
| 6 | 5s | 92.632996 | .00015824 |
| 7 | 5s | 19.396715 | .00056602 |
| ORB.ENERGY,a.u. | -144.680000 |
| NORM | 1.000000 | < R > | .085222 | < R2 > | .009715 | < 1/R > | 17.671674 | < 1/R**2 > | 627.715348 |
Total Energy= -353.65014530 a.u.
Kinetic Energy= 353.62939975 a.u.
Potential Energy= -707.27954505 a.u.
Virial Ratio = -2.00005866