(1s 2 2s 1 5p 1 ) 1 P Ar 14+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1151.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 5p- electron | |
| 1 | 2p | 2.258458 | 5.55234942 |
| 2 | 3p | 3.706470 | -6.62547065 |
| 3 | 4p | 2.898154 | 7.70427865 |
| 4 | 5p | 2.962712 | -7.97953702 |
| 5 | 2p | 13.072047 | .01712804 |
| 6 | 5p | 20.777606 | .00074147 |
| 7 | 4p | 40.786920 | -.00014582 |
| 8 | 5p | 1.478687 | -.03200366 |
| 9 | 4p | 1.305401 | .03546076 |
| ORB.ENERGY,a.u. | -4.582800 | ||
| NORM | 1.000000 | < R > | 2.391943 | < R2 > | 6.441721 | < 1/R > | .611027 | < 1/R**2 > | 1.278284 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 14.633668 | .43868076 |
| 2 | 2s | 7.889884 | -.81941242 |
| 3 | 3s | 9.557515 | -.30449093 |
| 4 | 5s | 15.836026 | -.01860668 |
| 5 | 4s | 31.352176 | .00561331 |
| 6 | 5s | 40.878198 | -.00144197 |
| 7 | 3s | 70.889314 | .00005245 |
| 8 | 5s | 2.366064 | .00122133 |
| 9 | 4s | 1.998270 | -.00118898 |
| ORB.ENERGY,a.u. | -33.175000 | ||
| NORM | 1.000000 | < R > | .358612 | < R2 > | .149983 | < 1/R > | 4.125379 | < 1/R**2 > | 68.519731 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.359727 | .93847245 |
| 2 | 1s | 27.359797 | .04905243 |
| 3 | 2s | 21.933305 | .01688074 |
| 4 | 3s | 9.128165 | .00044077 |
| 5 | 4s | 70.805391 | -.00042107 |
| 6 | 5s | 94.006274 | .00015580 |
| 7 | 5s | 19.069730 | .00051654 |
| ORB.ENERGY,a.u. | -144.680000 |
| NORM | 1.000000 | < R > | .085211 | < R2 > | .009713 | < 1/R > | 17.673170 | < 1/R**2 > | 627.799486 |
Total Energy= -351.03310885 a.u.
Kinetic Energy= 351.02325889 a.u.
Potential Energy= -702.05636775 a.u.
Virial Ratio = -2.00002806