(1s 2 2s 2 5p 1 ) 2 P Ar 13+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 2151.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 5p- electron | |
| 1 | 2p | 2.150776 | 4.05467188 |
| 2 | 3p | 3.488801 | -5.64106604 |
| 3 | 4p | 2.858153 | 6.85482794 |
| 4 | 5p | 2.815465 | -6.45033495 |
| 5 | 2p | 10.076833 | .06931360 |
| 6 | 5p | 10.184685 | .02809269 |
| 7 | 4p | 13.323014 | .01626650 |
| 8 | 5p | 1.642047 | -.00234257 |
| 9 | 5p | 52.111864 | -.00005575 |
| ORB.ENERGY,a.u. | -4.059300 | ||
| NORM | 1.000001 | < R > | 2.520416 | < R2 > | 7.150320 | < 1/R > | .579570 | < 1/R**2 > | 1.166864 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 14.944284 | .41546246 |
| 2 | 2s | 7.512010 | -.82045067 |
| 3 | 3s | 9.661717 | -.29022666 |
| 4 | 5s | 17.840871 | -.01350573 |
| 5 | 4s | 35.665503 | .00204841 |
| 6 | 5s | 52.805839 | -.00030407 |
| 7 | 5s | 7.697583 | .00390564 |
| ORB.ENERGY,a.u. | -4.969700 | ||
| NORM | 1.000000 | < R > | .364826 | < R2 > | .155404 | < 1/R > | 4.040828 | < 1/R**2 > | 65.733680 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.084146 | .93388417 |
| 2 | 1s | 26.731382 | .06462591 |
| 3 | 2s | 18.810640 | .01955699 |
| 4 | 3s | 20.279456 | -.01686667 |
| 5 | 5s | 40.727414 | .00079083 |
| 6 | 4s | 90.210664 | -.00005479 |
| 7 | 5s | 17.660545 | -.00018511 |
| ORB.ENERGY,a.u. | -144.120000 |
| NORM | 1.000000 | < R > | .085229 | < R2 > | .009715 | < 1/R > | 17.669027 | < 1/R**2 > | 627.517292 |
Total Energy= -381.58996867 a.u.
Kinetic Energy= 381.58995161 a.u.
Potential Energy= -763.17992028 a.u.
Virial Ratio = -2.00000004