(1s 2 2s 2 2p 1 3s 1 ) 1 P Ar 12+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1130.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 3s- electron | |
| 1 | 1s | 13.642713 | .22027368 |
| 2 | 2s | 5.136607 | -1.39989433 |
| 3 | 3s | 4.677448 | 1.98095243 |
| 4 | 4s | 9.943226 | -.06083859 |
| 5 | 5s | 19.026430 | -.00679817 |
| 6 | 4s | 35.332722 | .00052444 |
| 7 | 3s | 12.865634 | -.00437980 |
| 8 | 5s | 2.385620 | .00007222 |
| ORB.ENERGY,a.u. | -10.781000 | ||
| NORM | 1.000000 | < R > | .917697 | < R2 > | .950436 | < 1/R > | 1.554646 | < 1/R**2 > | 14.350317 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 7.624383 | 1.06999953 |
| 2 | 3p | 9.322967 | -.08179277 |
| 3 | 2p | 18.096023 | .01310291 |
| 4 | 5p | 27.422102 | .00276088 |
| 5 | 5p | 30.842071 | -.00108346 |
| 6 | 4p | 2.326992 | -.00003085 |
| ORB.ENERGY,a.u. | -26.367000 | ||
| NORM | 1.000000 | < R > | .321172 | < R2 > | .124657 | < 1/R > | 3.928575 | < 1/R**2 > | 20.839313 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 15.102406 | .40241910 |
| 2 | 2s | 7.331846 | -.81495693 |
| 3 | 3s | 9.568883 | -.28842502 |
| 4 | 4s | 34.657837 | .00128895 |
| 5 | 5s | 18.786222 | -.01075073 |
| 6 | 5s | 5.605741 | .00626519 |
| 7 | 3s | 67.406150 | .00001919 |
| ORB.ENERGY,a.u. | -26.841000 | ||
| NORM | 1.000000 | < R > | .370141 | < R2 > | .159973 | < 1/R > | 3.975964 | < 1/R**2 > | 63.818910 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.235625 | .95880393 |
| 2 | 1s | 29.092605 | .03929631 |
| 3 | 2s | 17.223117 | .02206635 |
| 4 | 3s | 21.486483 | -.01877274 |
| 5 | 4s | 90.426487 | -.00006279 |
| 6 | 5s | 38.959820 | .00103289 |
| 7 | 5s | 6.956684 | -.00131391 |
| 8 | 3s | 5.054528 | .00126391 |
| 9 | 4s | 4.422874 | -.00047468 |
| ORB.ENERGY,a.u. | -137.760000 |
| NORM | 1.000000 | < R > | .085428 | < R2 > | .009771 | < 1/R > | 17.642016 | < 1/R**2 > | 626.012872 |
Total Energy= -416.01569165 a.u.
Kinetic Energy= 415.95484408 a.u.
Potential Energy= -831.97053573 a.u.
Virial Ratio = -2.00014628