(1s 2 2s 2 2p 1 5s 1 ) 1 P Si 8+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1150.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 5s- electron | |
| 1 | 1s | 11.077846 | .08330588 |
| 2 | 2s | 2.920524 | -1.07314533 |
| 3 | 3s | 2.573757 | 3.34435721 |
| 4 | 4s | 1.876558 | -8.41427660 |
| 5 | 5s | 1.903710 | 6.88911731 |
| 6 | 5s | 16.752078 | -.00467942 |
| 7 | 4s | 8.326789 | -.02901660 |
| 8 | 4s | 26.090285 | -.00030159 |
| 9 | 5s | 1.190699 | -.00173599 |
| ORB.ENERGY,a.u. | -1.801100 | ||
| NORM | 1.000000 | < R > | 3.758917 | < R2 > | 15.811933 | < 1/R > | .384615 | < 1/R**2 > | 1.438835 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 5.649173 | 1.10512444 |
| 2 | 3p | 7.045599 | -.12803697 |
| 3 | 2p | 13.850819 | .01440723 |
| 4 | 5p | 11.395501 | .00801569 |
| 5 | 4p | 2.640732 | -.00061027 |
| 6 | 5p | 18.259919 | .00405325 |
| 7 | 5p | 3.750643 | .00126396 |
| ORB.ENERGY,a.u. | -14.379000 | ||
| NORM | 1.000000 | < R > | .431355 | < R2 > | .225384 | < 1/R > | 2.933260 | < 1/R**2 > | 11.659876 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 12.483145 | .35092135 |
| 2 | 2s | 4.746065 | -.83028513 |
| 3 | 3s | 7.854301 | -.32183021 |
| 4 | 4s | 5.223254 | .11266626 |
| 5 | 5s | 15.814291 | -.01127967 |
| 6 | 5s | 1.656853 | .02505210 |
| 7 | 4s | 1.467394 | -.02450761 |
| 8 | 3s | 18.022450 | -.00010241 |
| 9 | 5s | 36.253589 | .00035179 |
| ORB.ENERGY,a.u. | -14.065000 | ||
| NORM | 1.000000 | < R > | .493832 | < R2 > | .285556 | < 1/R > | 2.964991 | < 1/R**2 > | 35.571729 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 13.160829 | .92543404 |
| 2 | 1s | 20.204555 | .07508521 |
| 3 | 2s | 11.644560 | .01895633 |
| 4 | 3s | 14.582526 | -.01706357 |
| 5 | 4s | 70.205833 | -.00006350 |
| 6 | 5s | 32.423658 | .00084081 |
| 7 | 5s | 2.392177 | .00115320 |
| 8 | 3s | 1.329764 | -.00120483 |
| ORB.ENERGY,a.u. | -79.321000 |
| NORM | 1.000000 | < R > | .110553 | < R2 > | .016380 | < 1/R > | 13.648793 | < 1/R**2 > | 375.247326 |
Total Energy= -240.36308617 a.u.
Kinetic Energy= 240.35640703 a.u.
Potential Energy= -480.71949320 a.u.
Virial Ratio = -2.00002779