(1s 2 2s 2 2p 1 5p 1 ) 1 P Si 8+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1151.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 5p- electron | |
| 1 | 2p | 4.809621 | .34184517 |
| 2 | 3p | 2.168989 | -3.26745438 |
| 3 | 4p | 1.877692 | 8.99964325 |
| 4 | 5p | 1.883297 | -6.68847795 |
| 5 | 2p | 11.569614 | .00821581 |
| 6 | 5p | 6.031979 | .05482721 |
| 7 | 5p | 2.171709 | -.06965363 |
| 8 | 5p | 30.401932 | -.00019218 |
| 9 | 3p | 23.631023 | -.00019639 |
| ORB.ENERGY,a.u. | -1.744400 | ||
| NORM | .999997 | < R > | 3.771110 | < R2 > | 15.989591 | < 1/R > | .382945 | < 1/R**2 > | .513363 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 5.649970 | 1.10626919 |
| 2 | 3p | 7.000368 | -.12596619 |
| 3 | 2p | 14.072850 | .01386381 |
| 4 | 5p | 11.753520 | .00535005 |
| 5 | 4p | 3.188906 | -.00060862 |
| 6 | 5p | 18.204893 | .00354925 |
| 7 | 5p | 4.251720 | .00140314 |
| ORB.ENERGY,a.u. | -14.398000 | ||
| NORM | 1.000000 | < R > | .431036 | < R2 > | .225066 | < 1/R > | 2.935461 | < 1/R**2 > | 11.676650 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 12.152929 | .36487872 |
| 2 | 2s | 5.188582 | -.80585246 |
| 3 | 3s | 7.621505 | -.28115671 |
| 4 | 4s | 26.394751 | .00138761 |
| 5 | 5s | 14.791729 | -.01173195 |
| 6 | 5s | 5.782568 | .01967332 |
| ORB.ENERGY,a.u. | -14.065000 | ||
| NORM | 1.000000 | < R > | .494285 | < R2 > | .285978 | < 1/R > | 2.961630 | < 1/R**2 > | 35.493613 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 13.162246 | .92573326 |
| 2 | 1s | 20.229460 | .07470351 |
| 3 | 2s | 11.718810 | .01892863 |
| 4 | 3s | 14.614126 | -.01690904 |
| 5 | 4s | 69.122397 | -.00006958 |
| 6 | 5s | 32.281887 | .00079675 |
| 7 | 4s | 3.817331 | .00001778 |
| ORB.ENERGY,a.u. | -79.321000 |
| NORM | 1.000000 | < R > | .110555 | < R2 > | .016379 | < 1/R > | 13.648574 | < 1/R**2 > | 375.237998 |
Total Energy= -240.28623055 a.u.
Kinetic Energy= 240.30104386 a.u.
Potential Energy= -480.58727441 a.u.
Virial Ratio = -1.99993836