(1s 2 2s 2 2p 1 5d 1 ) 3 P Ar 12+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 3152.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 5d- electron | |
| 1 | 3d | 3.329063 | 1.50648538 |
| 2 | 4d | 2.755714 | -4.53882013 |
| 3 | 5d | 2.579519 | 3.77493346 |
| 4 | 3d | 7.402840 | .02304344 |
| 5 | 5d | 2.089919 | -.10438231 |
| 6 | 5d | 19.993425 | -.00049593 |
| 7 | 4d | 14.369644 | .00472299 |
| 8 | 4d | 1.773656 | .05095401 |
| 9 | 3d | 23.517374 | .00030522 |
| ORB.ENERGY,a.u. | -3.435100 | ||
| NORM | 1.000000 | < R > | 2.606961 | < R2 > | 7.714291 | < 1/R > | .533333 | < 1/R**2 > | .585327 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 7.628227 | 1.07221104 |
| 2 | 3p | 9.146362 | -.08554711 |
| 3 | 2p | 18.138302 | .01317808 |
| 4 | 5p | 23.162508 | .00257977 |
| 5 | 5p | 7.360469 | .00028900 |
| ORB.ENERGY,a.u. | -27.181000 | ||
| NORM | 1.000000 | < R > | .320192 | < R2 > | .123887 | < 1/R > | 3.939396 | < 1/R**2 > | 20.943647 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 15.372875 | .39054727 |
| 2 | 2s | 7.028959 | -.81752937 |
| 3 | 3s | 10.031024 | -.28747792 |
| 4 | 4s | 33.310039 | .00116970 |
| 5 | 5s | 19.581232 | -.00819168 |
| 6 | 5s | 7.820826 | .01799816 |
| ORB.ENERGY,a.u. | -26.841000 | ||
| NORM | 1.000000 | < R > | .371526 | < R2 > | .161388 | < 1/R > | 3.962425 | < 1/R**2 > | 63.424213 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.203003 | .93915180 |
| 2 | 1s | 26.416011 | .05729779 |
| 3 | 2s | 15.929878 | .02015394 |
| 4 | 3s | 19.420594 | -.01417688 |
| 5 | 4s | 86.740085 | -.00006091 |
| 6 | 5s | 41.403583 | .00061849 |
| 7 | 5s | 10.391941 | .00004410 |
| ORB.ENERGY,a.u. | -137.760000 |
| NORM | 1.000000 | < R > | .085399 | < R2 > | .009762 | < 1/R > | 17.646018 | < 1/R**2 > | 626.240601 |
Total Energy= -408.65517010 a.u.
Kinetic Energy= 408.64575870 a.u.
Potential Energy= -817.30092880 a.u.
Virial Ratio = -2.00002303