(1s 2 2s 2 2p 2 4s 1 ) 2 P Ar 11+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 2140.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4s- electron | |
| 1 | 1s | 13.813874 | .12886754 |
| 2 | 2s | 3.879263 | -1.61812429 |
| 3 | 3s | 3.506177 | 4.28255543 |
| 4 | 4s | 3.215069 | -3.13538243 |
| 5 | 5s | 4.629908 | -.26269779 |
| 6 | 4s | 13.491069 | -.00763468 |
| 7 | 5s | 40.908685 | .00043884 |
| 8 | 5s | 2.777576 | .00886987 |
| 9 | 4s | 60.089118 | .00004311 |
| 10 | 4s | 1.584312 | -.00075909 |
| ORB.ENERGY,a.u. | -5.108500 | ||
| NORM | .999999 | < R > | 1.772846 | < R2 > | 3.529068 | < 1/R > | .809980 | < 1/R**2 > | 5.148691 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 7.190157 | 1.14177000 |
| 2 | 3p | 7.951080 | -.15894465 |
| 3 | 2p | 17.292755 | .02095791 |
| 4 | 4p | 17.228480 | .00362384 |
| 5 | 5p | 14.923851 | -.00934545 |
| 6 | 5p | 2.400967 | .00005242 |
| 7 | 4p | 74.526314 | .00002147 |
| ORB.ENERGY,a.u. | -24.463000 | ||
| NORM | 1.000000 | < R > | .328543 | < R2 > | .130799 | < 1/R > | 3.851909 | < 1/R**2 > | 20.101147 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 13.822831 | .44979146 |
| 2 | 3s | 1.972667 | .01734091 |
| 3 | 2s | 8.145015 | -.88327867 |
| 4 | 3s | 8.222832 | -.28850189 |
| 5 | 4s | 31.054330 | .00183843 |
| 6 | 3s | 15.558049 | .02614339 |
| 7 | 5s | 8.888257 | -.03150331 |
| 8 | 4s | 2.555211 | -.02100867 |
| 9 | 5s | 1.823658 | -.00117666 |
| ORB.ENERGY,a.u. | -23.662000 | ||
| NORM | 1.000000 | < R > | .378024 | < R2 > | .167399 | < 1/R > | 3.890238 | < 1/R**2 > | 61.335455 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.134021 | .90302802 |
| 2 | 1s | 24.485573 | .08793660 |
| 3 | 2s | 17.792194 | .01777907 |
| 4 | 3s | 8.935397 | -.03045463 |
| 5 | 5s | 17.118778 | .01306715 |
| 6 | 3s | 51.134020 | -.00030315 |
| 7 | 5s | 11.312809 | .01762656 |
| 8 | 4s | 2.492542 | .00135353 |
| 9 | 3s | 1.943545 | -.00085862 |
| ORB.ENERGY,a.u. | -133.590000 |
| NORM | 1.000000 | < R > | .085573 | < R2 > | .009811 | < 1/R > | 17.622680 | < 1/R**2 > | 624.945718 |
Total Energy= -435.51787509 a.u.
Kinetic Energy= 435.49230858 a.u.
Potential Energy= -871.01018367 a.u.
Virial Ratio = -2.00005871