(1s 2 2s 2 2p 2 4d 1 ) 2 P Ar 11+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 2142.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4d- electron | |
| 1 | 3d | 3.532303 | 1.25578794 |
| 2 | 4d | 3.006025 | -1.78204865 |
| 3 | 3d | 7.225043 | .05189579 |
| 4 | 5d | 10.643466 | -.00890343 |
| 5 | 4d | 29.864160 | .00007235 |
| 6 | 5d | 2.636046 | .00967637 |
| 7 | 3d | 34.162257 | .00003388 |
| ORB.ENERGY,a.u. | -4.637900 | ||
| NORM | 1.000000 | < R > | 1.689679 | < R2 > | 3.270080 | < 1/R > | .785402 | < 1/R**2 > | 1.015999 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 7.221632 | 1.12805093 |
| 2 | 3p | 8.232582 | -.15424649 |
| 3 | 2p | 17.032462 | .02198076 |
| 4 | 4p | 20.312653 | .00689898 |
| 5 | 5p | 29.765122 | -.00115082 |
| 6 | 5p | 6.465696 | -.00116409 |
| 7 | 4p | 79.434850 | .00002877 |
| ORB.ENERGY,a.u. | -24.419000 | ||
| NORM | 1.000000 | < R > | .328600 | < R2 > | .130863 | < 1/R > | 3.851804 | < 1/R**2 > | 20.102069 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 14.053929 | .43773549 |
| 2 | 2s | 7.995901 | -.87199226 |
| 3 | 3s | 8.177804 | -.28712736 |
| 4 | 4s | 30.498871 | .00190776 |
| 5 | 3s | 16.561265 | .01635162 |
| 6 | 5s | 8.251990 | -.02058028 |
| ORB.ENERGY,a.u. | -23.662000 | ||
| NORM | 1.000000 | < R > | .378754 | < R2 > | .168005 | < 1/R > | 3.881584 | < 1/R**2 > | 61.074525 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.068397 | .92683051 |
| 2 | 1s | 25.712391 | .07171518 |
| 3 | 2s | 15.768831 | .01936993 |
| 4 | 3s | 19.682432 | -.01555106 |
| 5 | 5s | 42.443743 | .00077865 |
| 6 | 4s | 99.606263 | -.00003460 |
| 7 | 5s | 12.646704 | .00023222 |
| ORB.ENERGY,a.u. | -133.590000 |
| NORM | 1.000000 | < R > | .085562 | < R2 > | .009807 | < 1/R > | 17.624219 | < 1/R**2 > | 625.033687 |
Total Energy= -435.02780669 a.u.
Kinetic Energy= 435.03441561 a.u.
Potential Energy= -870.06222230 a.u.
Virial Ratio = -1.99998481