(1s 2 2s 2 2p 2 4d 1 ) 4 P Ar 11+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 4142.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4d- electron | |
| 1 | 3d | 3.497752 | 1.29375293 |
| 2 | 4d | 2.997746 | -1.81334877 |
| 3 | 3d | 7.257055 | .04459700 |
| 4 | 5d | 10.521642 | -.00788089 |
| 5 | 5d | 2.637345 | .01034946 |
| 6 | 4d | 27.953838 | .00010152 |
| 7 | 3d | 32.218353 | .00004747 |
| ORB.ENERGY,a.u. | -4.615900 | ||
| NORM | 1.000000 | < R > | 1.697850 | < R2 > | 3.302675 | < 1/R > | .781533 | < 1/R**2 > | 1.003449 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 7.174605 | 1.15739617 |
| 2 | 3p | 8.273594 | -.17825160 |
| 3 | 2p | 16.751238 | .02164635 |
| 4 | 4p | 18.527293 | .00458054 |
| 5 | 5p | 40.434301 | -.00022603 |
| 6 | 5p | 5.507139 | .00233273 |
| 7 | 4p | 6.339861 | -.00990026 |
| ORB.ENERGY,a.u. | -24.397000 | ||
| NORM | 1.000000 | < R > | .328522 | < R2 > | .130810 | < 1/R > | 3.852701 | < 1/R**2 > | 20.110701 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 14.053938 | .43773948 |
| 2 | 2s | 7.995941 | -.87199618 |
| 3 | 3s | 8.177952 | -.28712524 |
| 4 | 4s | 30.493595 | .00190498 |
| 5 | 3s | 16.564848 | .01635564 |
| 6 | 5s | 8.250582 | -.02058278 |
| ORB.ENERGY,a.u. | -23.662000 | ||
| NORM | 1.000000 | < R > | .378752 | < R2 > | .168004 | < 1/R > | 3.881616 | < 1/R**2 > | 61.075635 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.068188 | .92683738 |
| 2 | 1s | 25.715040 | .07170919 |
| 3 | 2s | 15.775174 | .01936630 |
| 4 | 3s | 19.686453 | -.01554998 |
| 5 | 5s | 42.488960 | .00077860 |
| 6 | 4s | 99.522539 | -.00003372 |
| 7 | 5s | 12.667154 | .00023355 |
| ORB.ENERGY,a.u. | -133.590000 |
| NORM | 1.000000 | < R > | .085562 | < R2 > | .009807 | < 1/R > | 17.624198 | < 1/R**2 > | 625.032474 |
Total Energy= -435.02763408 a.u.
Kinetic Energy= 435.01234171 a.u.
Potential Energy= -870.03997579 a.u.
Virial Ratio = -2.00003515