(1s 2 2s 2 2p 4 4d 1 ) 2 P Ar 9+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 2142.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4d- electron | |
| 1 | 3d | 2.789806 | 1.44071182 |
| 2 | 4d | 2.515240 | -1.97032946 |
| 3 | 3d | 8.558675 | .02756420 |
| 4 | 4d | 5.992736 | .02764412 |
| 5 | 5d | 28.722314 | -.00008165 |
| ORB.ENERGY,a.u. | -3.190800 | ||
| NORM | 1.000000 | < R > | 2.041185 | < R2 > | 4.781225 | < 1/R > | .654129 | < 1/R**2 > | .711956 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 6.506750 | 1.12935709 |
| 2 | 3p | 7.293201 | -.20588419 |
| 3 | 2p | 13.734400 | .07155873 |
| 4 | 4p | 16.366286 | .01323589 |
| 5 | 5p | 19.777882 | -.00061935 |
| 6 | 5p | 6.649779 | -.00166761 |
| 7 | 4p | 72.573721 | .00002187 |
| ORB.ENERGY,a.u. | -19.004000 | ||
| NORM | 1.000000 | < R > | .347990 | < R2 > | .147874 | < 1/R > | 3.669361 | < 1/R**2 > | 18.425706 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 14.158655 | .41599136 |
| 2 | 2s | 7.818216 | -.86239816 |
| 3 | 3s | 7.320503 | -.30212366 |
| 4 | 4s | 13.744473 | .00393305 |
| 5 | 3s | 17.609666 | .01400352 |
| 6 | 5s | 38.413911 | .00067429 |
| 7 | 5s | 7.169182 | -.00608307 |
| 8 | 4s | 3.623429 | .00015608 |
| 9 | 3s | 68.198332 | -.00003181 |
| ORB.ENERGY,a.u. | -20.023000 | ||
| NORM | 1.000000 | < R > | .393312 | < R2 > | .181830 | < 1/R > | 3.729535 | < 1/R**2 > | 56.750374 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.132489 | .91985419 |
| 2 | 1s | 24.600841 | .07653413 |
| 3 | 2s | 11.205253 | .02021457 |
| 4 | 3s | 13.630606 | -.02041680 |
| 5 | 4s | 16.404881 | .00883582 |
| 6 | 5s | 44.068365 | .00072906 |
| 7 | 4s | 106.248094 | -.00002405 |
| ORB.ENERGY,a.u. | -127.520000 |
| NORM | 1.000000 | < R > | .085840 | < R2 > | .009885 | < 1/R > | 17.587591 | < 1/R**2 > | 623.015539 |
Total Energy= -476.16099562 a.u.
Kinetic Energy= 476.10579811 a.u.
Potential Energy= -952.26679374 a.u.
Virial Ratio = -2.00011594