(1s 2 2s 2 2p 5 4p 1 ) 1 P Na +
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 1141.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4p- electron | |
| 1 | 2p | 4.053369 | .12413756 |
| 2 | 3p | .460341 | 1.80644881 |
| 3 | 4p | 1.182874 | -.48866893 |
| 4 | 5p | 2.296768 | -.08917455 |
| 5 | 3p | 5.618432 | -.02758483 |
| 6 | 5p | .535864 | -.69168353 |
| 7 | 4p | 15.839426 | -.00037374 |
| 8 | 3p | .708479 | -.71857705 |
| 9 | 4p | .554791 | .52599797 |
| 10 | 2p | 25.359304 | .00002794 |
| ORB.ENERGY,a.u. | -.177940 | ||
| NORM | .999997 | < R > | 8.002085 | < R2 > | 72.582570 | < 1/R > | .169523 | < 1/R**2 > | .084070 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 2.833315 | 1.39713394 |
| 2 | 3p | 3.452068 | -.50269025 |
| 3 | 2p | 7.677960 | .10472081 |
| 4 | 4p | 8.421479 | .02799544 |
| 5 | 5p | 2.203826 | .05089464 |
| 6 | 4p | 1.943476 | -.05825042 |
| 7 | 5p | 14.256880 | .00180558 |
| 8 | 3p | .599140 | .00065709 |
| ORB.ENERGY,a.u. | -2.371800 | ||
| NORM | 1.000000 | < R > | .738817 | < R2 > | .689590 | < 1/R > | 1.796535 | < 1/R**2 > | 4.608227 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 9.131676 | .32075476 |
| 2 | 2s | 4.171838 | -.80962616 |
| 3 | 3s | 3.328037 | -.31892031 |
| 4 | 4s | 14.787734 | .01191573 |
| 5 | 3s | 21.079418 | .00171147 |
| 6 | 5s | 27.671911 | .00062250 |
| 7 | 5s | 2.306258 | -.00444425 |
| 8 | 4s | 2.581312 | .00588183 |
| 9 | 3s | 1.316023 | .00139343 |
| 10 | 2s | 74.012563 | .00000329 |
| ORB.ENERGY,a.u. | -2.975600 | ||
| NORM | 1.000000 | < R > | .753247 | < R2 > | .678504 | < 1/R > | 1.926459 | < 1/R**2 > | 15.307953 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 10.229865 | .91337159 |
| 2 | 1s | 15.493172 | .08642338 |
| 3 | 2s | 5.347415 | .01504162 |
| 4 | 3s | 7.014133 | -.01793838 |
| 5 | 4s | 9.110008 | .01105944 |
| 6 | 5s | 25.883765 | .00104595 |
| 7 | 4s | 58.386941 | -.00005798 |
| ORB.ENERGY,a.u. | -39.982000 |
| NORM | 1.000000 | < R > | .142774 | < R2 > | .027439 | < 1/R > | 10.610968 | < 1/R**2 > | 227.648744 |
Total Energy= -160.17668747 a.u.
Kinetic Energy= 160.17533310 a.u.
Potential Energy= -320.35202057 a.u.
Virial Ratio = -2.00000846