(1s 2 2s 2 2p 5 4d 1 ) 3 P Ar 8+
F( r ) = Σ j C j S nl ( α j ,r) Y l,m ( r )
Table 3142.
N.V.Novikov // Wave Function Value Database;
http://cdfe.sinp.msu.ru/services/wftables/
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 4d- electron | |
| 1 | 3d | 2.709870 | 1.15069754 |
| 2 | 4d | 2.296350 | -1.70949669 |
| 3 | 3d | 7.850362 | .04247467 |
| 4 | 5d | 24.802971 | -.00012313 |
| 5 | 4d | 5.732347 | .05076942 |
| ORB.ENERGY,a.u. | -2.663000 | ||
| NORM | 1.000001 | < R > | 2.194179 | < R2 > | 5.529517 | < 1/R > | .612577 | < 1/R**2 > | .637629 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2p- electron | |
| 1 | 2p | 6.391544 | 1.16992928 |
| 2 | 3p | 7.552524 | -.23243867 |
| 3 | 2p | 14.010467 | .06125198 |
| 4 | 4p | 17.011206 | .00950365 |
| 5 | 5p | 3.455558 | -.00038493 |
| 6 | 4p | 4.451658 | .00111058 |
| 7 | 4p | 71.511750 | .00002086 |
| ORB.ENERGY,a.u. | -16.959000 | ||
| NORM | 1.000000 | < R > | .359238 | < R2 > | .158318 | < 1/R > | 3.573660 | < 1/R**2 > | 17.581748 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 2s- electron | |
| 1 | 1s | 14.333943 | .40027486 |
| 2 | 2s | 7.682217 | -.84639844 |
| 3 | 3s | 7.003324 | -.30628492 |
| 4 | 4s | 19.108445 | .00465587 |
| 5 | 3s | 21.171203 | .00696780 |
| 6 | 5s | 38.478598 | .00053849 |
| 7 | 5s | 6.072423 | -.00352345 |
| 8 | 4s | 4.356795 | .00149946 |
| 9 | 3s | 3.393421 | -.00037731 |
| 10 | 2s | 95.520487 | .00000654 |
| ORB.ENERGY,a.u. | -18.309000 | ||
| NORM | 1.000000 | < R > | .400939 | < R2 > | .189357 | < 1/R > | 3.655358 | < 1/R**2 > | 54.686213 |
| j | S nl j (α j ,r) | C j | |
| nl j | α j | 1s- electron | |
| 1 | 1s | 17.190903 | .93053003 |
| 2 | 1s | 25.174961 | .06482562 |
| 3 | 2s | 10.855842 | .02185275 |
| 4 | 3s | 13.392003 | -.02196939 |
| 5 | 4s | 16.616937 | .01065805 |
| 6 | 5s | 43.001793 | .00068782 |
| 7 | 4s | 98.882661 | -.00003187 |
| ORB.ENERGY,a.u. | -124.690000 |
| NORM | 1.000000 | < R > | .085954 | < R2 > | .009918 | < 1/R > | 17.572762 | < 1/R**2 > | 622.203245 |
Total Energy= -493.11896682 a.u.
Kinetic Energy= 493.14247650 a.u.
Potential Energy= -986.26144332 a.u.
Virial Ratio = -1.99995233