(1s1s) 1 S Z=23 V 21+
Table 1. Novikov N.V. // Wave Function Value Database http://cdfe.sinp.msu.ru/services/wftables/
j | R n1,l1 (α1,r) | R n2,l2 (α2,r) | g | ||
n1 l1 | α1 | n2 l2 | α2 | ||
1 | 1s | 20.5413 | 1s | 24.7963 | 0.7137537720671883E+00 |
2 | 1s | 37.7684 | 4s | 156.0962 | 0.7208913097878602E-03 |
3 | 1s | 59.0063 | 2s | 69.4237 | -0.1577395836268486E-02 |
4 | 2s | 177.6844 | 4s | 176.7094 | 0.4211147255196411E-03 |
5 | 1s | 30.2951 | 3s | 65.5011 | -0.6330995958235959E-02 |
6 | 1s | 39.5238 | 2s | 70.8719 | 0.4532336452626645E-02 |
7 | 2s | 85.7902 | 3s | 100.5147 | -0.7137537720671883E-03 |
8 | 3s | 161.9744 | 4s | 158.7584 | -0.9064672905253292E-03 |
9 | 4s | 191.9935 | 5s | 222.6400 | -0.3640144237542661E-03 |
10 | 2p | 60.3064 | 2p | 60.3064 | 0.6480884250370069E-02 |
11 | 2p | 123.0088 | 3p | 129.3057 | 0.1134868497586829E-02 |
12 | 4p | 183.3228 | 4p | 183.3228 | 0.4639399518436724E-03 |
13 | 2p | 70.6369 | 4p | 162.5236 | -0.8208168378772665E-03 |
14 | 3p | 319.4143 | 4p | 310.9999 | 0.1142006035307501E-03 |
15 | 3d | 158.5466 | 3d | 158.5466 | -0.1099180808983470E-02 |
16 | 4d | 243.0481 | 4d | 243.0481 | -0.5067651781677036E-03 |
17 | 5d | 334.9983 | 5d | 334.9983 | -0.1855759807374689E-03 |
18 | 3d | 79.4475 | 5d | 221.0644 | -0.1641633675754533E-03 |
19 | 4f | 263.6309 | 4f | 263.6309 | 0.4282522632403129E-03 |
20 | 5f | 344.7509 | 5f | 344.7509 | 0.2141261316201565E-03 |
21 | 5g | 384.6761 | 5g | 384.6761 | -0.1998510561788127E-03 |
Energy= -514.78132447 a.u.
Table 1. Clementi E., Roetti C.// At. Data Nucl. Data Tables 14, 177, (1974)
Ψ( r 1 , r 2 ) = F( r 1 ) F( r 2 ) ; F( r ) = Σ j C j φ 1s ( α j , r )
j | R n,l (α,r) | C | |
n l | α | ||
1 | 1s | 22.45530 | 0.98687 |
2 | 1s | 42.04130 | 0.01825 |
3 | 1s | 51.49010 | -0.00345 |
Energy= -514.73605 a.u.